https://the-trudgians.com/tyre-pressure-calculator/
This is often linked from caravan sites and it appears to be logical. Essentially, it assumes the max tyre pressure on the sidewall is required to support the max load of the tyre - the pressure reduces as the load reduces in the same proportion as max PSI/Max load (the link above explains it much better!)
In my case the tyre has a max pressure of 50PSI and rating of 500kg, so to support a 2T load over 2 axles the tyre pressure needs to be 50PSI.
I'm packing for holidays, so the boat has been emptied of fuel, water, lines etc and the tyres pumped to 50PSI. I'd like to take it to a weighbridge, but apparently Surrey don't have any!